Evaluation of Photocatalytic Activity of the TiO2 Layer Formed on Ti by Thermal Oxidation

نویسندگان

  • Takayuki Narushima
  • Shota Sado
  • Natsumi Kondo
  • Kyosuke Ueda
  • Mitsuko Kawano
  • Kouetsu Ogasawara
چکیده

Two-step thermal oxidation was proposed for Ti and Ti alloys as a surface-treatment process for preparing an anatase-containing TiO2 layer. This process consisted of treatment in a CO-containing atmosphere (first step) and subsequent treatment in air (second step). In this chapter, first, the current status of TiO2 coating onto Ti and Ti alloys for biomedical applications is reviewed; then our recent work on the phase and microstructure of TiO2 layers prepared on commercially pure (CP) Ti, Ti-25mass%Mo alloy, and Ti-25mass%Nb alloy by two-step thermal oxidation is described. The anatase fraction in the TiO2 layer was controlled through process parameters such as the second-step temperature. Finally, photocatalytic activity of TiO2 layers formed on the Ti and Ti alloys is evaluated, including: results of water contact angle, decomposition of methylene blue, and antibacterial effects.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Carbon coating stabilized Ti(3+)-doped TiO2 for photocatalytic hydrogen generation under visible light irradiation.

Self-doping by Ti(3+) is a useful method to expand the light response of TiO2 into the visible light region. However, to obtain a stable Ti(3+)-doped TiO2 seems to be a challenge due to the easy oxidation of Ti(3+) during the heterogeneous reaction. Here, we propose a simple carbon coating route to stabilize the Ti(3+)-doped TiO2, in which both the Ti(3+) and precursor of the carbon coating lay...

متن کامل

A strategy for degradation of 2,5-dichlorophenol using its photoelectrocatalytic oxidation on the TiO2/Ti thin film electrode

In this work, the photoelectrocatalytic (PEC) degradation of 2,5-dichlorophenol can be used for its removal from aqueous solution. To study this activity, a TiO2 thin film modified titanium sheet (TiO2/Ti) was fabricated by anodizing Ti plates using a two electrode system under the constant bias voltage of 20 V for 20 min in a solution of 0.2% (v/v) HF followed by calcinat...

متن کامل

Design of Highly Uniform Platinum and Palladium Nanoparticle Decoration on TiO2 Nanotube Arrays: An Efficient Anode to the Electro-Oxidation of Alcohols

We explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized TiO2 matrix. These electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to TiO2 nanotubes, respectively. Titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (EG) fluoride-c...

متن کامل

Photocatalytic oxidation of an organophosphorus simulant of chemical warfare agent by modified TiO2 nanophotocatalysts

TiO2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (DMMP) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. The prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. Transition metal ions including Pt...

متن کامل

Photocatalytic oxidation of an organophosphorus simulant of chemical warfare agent by modified TiO2 nanophotocatalysts

TiO2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (DMMP) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. The prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. Transition metal ions including Pt...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014